Semiconductors are very similar to insulators. The two categories of solids differ primarily in that insulators have larger band gaps—energies that electrons must acquire to be free to move from atom to atom. In semiconductors at room temperature, just as in insulators, very few electrons gain enough thermal energy to leap the band gap from the valence band to the conduction band, which is necessary for electrons to be available for electric current conduction. For this reason, pure semiconductors and insulators in the absence of applied electric fields, have roughly similar resistance. The smaller bandgaps of semiconductors, however, allow for other means besides temperature to control their electrical properties.
Semiconductors' intrinsic electrical properties are often permanently modified by introducing impurities by a process known as doping. Usually, it is sufficient to approximate that each impurity atom adds one electron or one "hole" (a concept to be discussed later) that may flow freely. Upon the addition of a sufficiently large proportion of impurity dopants, semiconductors will conduct electricity nearly as well as metals. Depending on the kind of impurity, a doped region of semiconductor can have more electrons or holes, and is named N-type or P-type semiconductor material, respectively. Junctions between regions of N- and P-type semiconductors create electric fields, which cause electrons and holes to be available to move away from them, and this effect is critical to semiconductor device operation. Also, a density difference in the amount of impurities produces a small electric field in the region which is used to accelerate non-equilibrium electrons or holes.
In addition to permanent modification through doping, the resistance of semiconductors is normally modified dynamically by applying electric fields. The ability to control resistance/conductivity in regions of semiconductor material dynamically through the application of electric fields is the feature that makes semiconductors useful. It has led to the development of a broad range of semiconductor devices, like transistors and diodes. Semiconductor devices that have dynamically controllable conductivity, such as transistors, are the building blocks of integrated circuits devices like the microprocessor. These "active" semiconductor devices (transistors) are combined with passive components implemented from semiconductor material such as capacitors and resistors, to produce complete electronic circuits.
In most semiconductors, when electrons lose enough energy to fall from the conduction band to the valence band (the energy levels above and below the band gap), they often emit light. This photoemission process underlies the light-emitting diode (LED) and the semiconductor laser, both of which are very important commercially. Conversely, semiconductor absorption of light in photodetectors excites electrons to move from the valence band to the higher energy conduction band, thus facilitating detection of light and vary with its intensity. This is useful for fiber optic communications, and providing the basis for energy from solar cells.
Semiconductors may be elemental materials such as silicon and germanium, or compound semiconductors such as gallium arsenide and indium phosphide, or alloys such as silicon germanium or aluminium gallium arsenide.

[edit] Band structure

atoms - crystal - vacuum

In a single H-atom an electron resides in well known orbits. Note that the orbits are called s,p,d in order of increasing circular current.

Putting two atoms together leads to delocalized orbits across two atoms, a so called covalent bond. Due to Paulis principle in every state there is max one electron.

This can be continued with more atoms. Note: This picture unfortunately shows a metal.

Using 6 carbon atoms one can create molecular orbits which allow for circular current. Filling the states following Pauli's principle leads to zero net current. Current due to uneven filling needs an energy investment.

Proceeding in a regular fashion and create a crystal, which may after creation be cut into a tape and fused together at the ends allow for circular currents.

For this regular solid the band structure can be calculated or measured.

Integrating over the k axis gives the bands of a semiconductor showing a full valence band and an empty conduction band. Generally stopping at the vacuum level is dumb, because some people want to calculate: photoemission, inverse photoemission, Semiconductor_detector#particle_detectors

After the band structure is determined states can be combined to generate wave packets. As this is analogous to wave packages in free space, the results are similar.

An alternative description, which does not really appreciate the strong Coulomb interaction, shoots free electrons into the crystal and looks at the scattering.

A third alternative description uses strongly localized unpaired electrons in chemical bonds, which looks almost like a Mott insulator.